Direction of heat flow

  • Entropy changes in the surroundings are primarily determined by heat flow 
    • Exothermic reactions in a system at constant temperature increase the entropy of the surroundings
    • Endothermic reactions in a system at constant temperature decrease the entropy of the surroundings
    • The impact of the transfer of a given quantity of energy as heat to or from the surroundings will be greater at lower temperatures
  • ∆Ssurr = - ∆H/T
  • Where ∆Ssurr is the entropy of the surrounding  ∆H is the enthalpy and T is the temperature in Kelvin