In 1938, Alvarez showed his first major discovery. It was the phenomenon of orbital electron capture . Before, in 1936 Hans Bethe had argued that an excited nucleus  could decay by capturing one of its own orbiting electrons . It is a process that is known as K-Capture . Alvarez succeeded in detecting the process experimentally by identifying the characteristic X rays emitted  during K capture , as a result of electrons moving from outer orbits into the vacant K orbit .